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in判決書

智慧財產及商業法院105年度民專訴字第66號

關鍵資訊

  • 裁判案由
    侵害專利權有關財產權爭議等
  • 案件類型
    智財
  • 審判法院
    智慧財產及商業法院
  • 裁判日期
    107 年 06 月 13 日

  • 當事人
    美商卡博特微電子公司

10566    Cabot MicroelectronicsCorporation  H. Carol Bernstein       Dongjin Semichem Co., Ltd.  Boo Sup Lee            Boo Sup Lee                 107 5 4 982259Cabot 151 3 1 7 2 1 3 421 107 2 139091 255 1 3 262 1 1 2 500 5 使DSW-2500漿Chemical-Mechanical Planarization Slurry116769漿198297162225使107 3 271 5,000 5%213 107 1 19162225使218 107 4 171 353 116769漿1 1982972 897 1 106 1125933 21107 7 27使漿961 1.1 1 8 1011212224283134351 1 4 9 11152122242835 2.2 pH9 2.6 pHTMAH2 1 TEA 2 1 2 1 6 111317242728303234 3.1 8 1011212224283134351 1 4 9 1115212224283134352 1 6 9 111317242728303234 4.使SEMICON Taiwan 2015 105 4 8 1 1 104 33106 130 106 102510606311740 1 713 1.1 201 漿/ CMP 漿漿5 % 漿1 211 漿/ CMP 漿漿5.0 % 漿2 1 2 漿 2.1 1 2 1 漿2 3 使676 / 291 385 / 漿5 6214/ 2 漿2 3 使Oxone 555 / 291 264 / 漿5 3396/ 3.使1 3 漿7 漿8 9 漿1 1 1 2 3 1 1 4 8 111521222428313435 1.1 1 -O-O- 1 2 1 漿5%使1 1 2.2 3 FentonCMP CMP 使CMP 2 3 CMP 2 3 CMP 2 3 使CMP 使2 3 CMP 3.2 3 3 1 1 3 1 CMP 2 3 CMP CMP 使1 3 CMP 1 2 3 1 1 4.1 8 1 3 1 CMP 使CMP 漿CMP 漿使1 3 1 8 CMP 1 4 9 1115212224283134351 3 1 2 711 3 1.2 1 pH9 7 pH9.0 1016pH9.0 pH9 使 2.2 9 pH105 7 pHpH4 使漿455052pH2.3 5.0 7.0 9 pH使9 pH 3.2 2.3 5.0 7.0 pHpH9 pH2 1 pH9 4 2 1 6 9 111322 1.4 2 1 pH9 2.4 4 BTA 2 2 4 0007使CMP 4 4 00107 CuCuBTA BTA W W BPA N--N- BPA 4 BTA CuW 4 3.2 4 漿/ 使漿pH使調pHpH 7.0CMP pH調 4.4 BTA 4 2 pH9 1 6 9 111322 5.4 4 2 4 BTA 4 BTA BPA 4 BPA BPA 2 BPA 2 使4 BTA BTA 2 BTA 2 4 BTA CMP 4 4 BTA CMP 6.2 BTA 4 BTA CMP 4 BTA 4 BTA BTA 2 1 4 1 6 9 111322 4 1 3 5 2 4 2 1 3 5 4 2 使2 2 使DSW-2500漿Chemical-Mechanical Planarization Slurry116769漿198297 1.1 1 4 8 111521222428313435711 3 1 1 2 使漿1 9 漿1 3 漿7 漿8 3 漿7 漿8 H2O29 漿1 0.02 wt%9 H2O 0.01wt% 3 漿7 9 漿1 使漿3 漿7 3374ang ./ min .使漿9 漿1 566 ang ./min . H2O21 漿使1 1 使83713 使 2.1 2 3 1 1 4 8 9 10111521222428313435 1 漿使1 1B-O-O- 2 3 使1 2 3 Fe+++ 使1+1> 21 1 1 2 3 4 1 1 8 4-201 4 1 1 4 1 1 8 4-20漿使漿2 9 2 Fe3+ ,Cu2+ , Cr3+ 3 1 Fe++Fe+++ 使1 2 3 CMP 使1 2 3 2 8 1 2 3 1 2 3 2 1 使1+1> 29 1 2 3 2 2627使2 10118 9 8 9 10112 1011 1 8 4-20EDTA1 159 9 151 1 8 4-20漿使2 9 2 Fe3+ ,Cu2+ , Cr3+ 3 1 Fe++Fe+++ 1 2 3 1 2 3 2 240.001 2.0 1 2 3 212224 1 漿4 21-23 漿1 281 8 9 1 8 9 281 28 1 4 21-23 漿1 292828291 29 1 1616-19 1 302929301 30 1 4 21-23 漿1 312828311 31 1 3 15-18 40/ 430 / 1.0 0.4 5 / 430 / 342828341 34 1 3 15-18 30/ 170 / 353434351 35 3.2 1 6 111317242728303234711 3 2 1 pH9 9 1 pH9 1 9 pH9 pH2 1 pHpH9 2 pH2.3 5.0 7.0 pH9 pHpH2 1 使711 3 4.4 2 1 6 111322 4 1 4 polishing 0007使2 0010benzotriazole BTA BTA tolyltriazole TTA 00110012使glycine amidosulfuric acidnitric acidhypochlorous acid 使potassiumferricyanide ethylendiam ine potassium ferricyanidepH7 pH9 4 2 1 退4 2 1 6 1 5 6 1 1 4 6 4 00110012使4 1112131 1 1112134 111213 221 4 0031使使4 2 2222退4 2 2222 5.2 3 4 2 1721 4 0012使2 9 2 Fe3+ , Cu2+ ,Cr3+ 3 1 ( Fe++Fe+++)使 4 2 3 ( Fe++Fe+++)4 2 3 2 3 4 2 20210.001 0.2 4 2 3 1721 6.1 4 2 2324272830 4 00311 WO96/11082漿4 21-23 漿1616 -19234 1 4 1 23 1 WO 96/11082 4 21-23 漿1 244 1 4 1 24 1 3 15-18 40/ 430 / 1.0 0.4 27284 1 4 1 2728 4 0031使1 1616304 1 4 1 30 7.1 2 4 5 2 3234 1 8 21-23 漿使2 2627Fe+++ 5 5 3 1 漿5 2 1 2 4 5 2 5 8.1 8 101121222428313435 LC/MS LC/MS SampleE LC/MS LC/MS Spectrum of Peak A1 CMP CMP 漿6 CMP 漿CMP 漿CMP 漿 1 8 167-11CMP 漿使 1 8 1011212224283134358 8 8 101121222428313435 9.1 1 4 9 111521222428313435 1 -O-O- 7 1 -O-O- 1 CMP 使使-O-O- 使-O-O- 1 4 9 1115212428351 1 1 1 4 9 1115212428313435 使使185 2 1 6 111317242728303234 8 1 1 CMP 使使使 2 1116使2 Benzisothiazolinone Benzisothiazolinone BIT CAS 0000-00-00001,2-Benzisothiazol-32H-onebiocide antimicrobialagentpreservative2 1 1 1 漿1 41/ 漿2-30漿8 漿14漿302,5--1,3 - 484547/ 2,5--1,3- 5 5 2 2 1 使 6 111317283032341 1 1 1 6 111317242728303234 1.photoresist stripperthinner DSW-2500漿CMP slurry 2. 1. 2.貿貿 3.232 995999280 99522 貿 4. 1 1 4 8 9 10111521222428313435713 2 1 6 111317242728303234713 1 2 3 1 1 4 8 9 10111521222428313435 4 2 1 6 111322 2 3 4 2 1721 1 4 2 2324272830 1 2 4 5 2 3234 1 8 101121222428313435 1 1 4 9 1115212224283134352 1 6 111317242728303234 1 1. 1 使1 1 1 Hawley's Condensed Chemical Dictionary-O-O- - - SO5=S2O8= 1 1020119 AgCoCrCuFeMoMnNbNiOsPdRuSnTiV / AgCuFeIIIII IIIII IIIII 1 1112161 EDTA 2. 1 48102 5 24103 6 21 1 -O-O- 4 1 8 9 -O-O- 108 9 1110 159 211 8 9 2221 241 8 9 0.001 2.0 281 8 9 2928 3029 3128 34285 430 353430170 2 1. 2 CMP 使2 4 1 6 2. 1 2 61105 3 28105 8 21106 12291 2 3 143644451 2 1 4 8-83780 671 2 2 1 4 00102 1 2 1 4 0010W 2 4 2 1 使20176.102-9-9 2 1 6732107 4 17351 1 1 pH9 6 1 5 111 5 1211 1312 171 5 1817 1918 20190.001 2.0 % 211 0.001 0.2 % 22漿1 5 2322漿 2422漿 2722漿5 / 430 / 2827漿30/ 170 / 3022漿 321 5 3322漿 343233漿 105 11105 5 5 2 250 500 3 MSDS1 105 11105 5 5 7 SampleF 7 2 9 1 1 3 105 1123( ) ( ) 106 8 17105 11298 8 1.1 19964 18PCT WO96/11082A1漿CHEMICAL MECHANICAL POLISHING SLURRY FOR METAL LAYERS 1 199611262 19977 281 2 1 漿漿1 漿EDTA1 8 4 13 2.2 1977119 Hydrogen Peroxide , PartFour , Chapter 9-12 1 199611262 19977 281 2 2 Fe3+Cu2+Cr3+2 9 2 3.3 19955 Fenton Reaction After a Century 1 199611262 19977 281 2 3 Fenton3 ( Fe++) ( Fe+++) 3 1.Introduction 4.4 19963 268-83780 2 19977 282 4 4 1 4 使CuCuAgAgAlAlW W 使benzotriazole BTA tolyltriazole TTA benzimidazole triazolecysteine4 00104 使4 00075.5 85101 2872082 19977 282 5 5 5 5 3 6 1 1 1 4 8 9 10111521222428313435713 1148910111521 222428313435713 1 1 1 1.1 1 1 1 201 漿CMP 漿漿5 漿1 211 漿/ CMP 漿漿5.0 漿2 1 2 漿1 2 1 1 2 1 漿2 3 使676 / 291 385 / 使1 漿5 6214/ 2 漿2 3 使Oxone 555 / 291 264 / 使Oxone 1 漿5 3396/ 1 1 1 漿3 5 5.0 % WCMP1 1 使1 漿2 3 使1 漿4 5 使1 1 2.1 1 1 使1 1 3. 1 16漿/ 1 1 9 漿使漿2 5 使漿1 9 漿2 5 漿1 1 9 1 167 8 4.1 使1 1 4 8 9 10111521222428313435713 1 2 3 1 1 4 8 111521222428313435 1.1 1 1 CMP CMP 使 1 漿漿8 4 20使( ) EDTA使1 漿5%使使1 5,244,534 1 CMP 使便CMP 5 1722漿H2O2H2O2CMP 2 2 9 2 Fe3+Cu2+Cr3+2 CMP CMP 使使CMP CMP 使2 CMP 使CMP 1+1> 22 9 1 1 1 5 使50°C 2 使CMP 使 3 Fenton3 1.IntroductionFe++ Fe+++ 3 CMP CMP 使使CMP 1 3 1 CMP 2 3 CMP CMP 使使1 2 3 CMP 1 2 3 1 1 2.4 1 4 1 1 1 2 3 1 1 1 4 3.8 1 8 1 3 1 使1 8 2 9 2627( ) 2 CMP 使CMP 使1 2 3 1 8 4.9 1 9 ( -O-O-)1 3 1 CMP 2 3 CMP 2 CMP 使2 使1 2 3 CMP 1 2 3 1 9 5.10111521222428313435 1 101115212224283134351 8 9 1 8 9 1 2 3 1 1 8 9 1 10111521222428313435 1 8 101121 222428313435 1.LC-MS 10654C00000-0-0-0010654C00000-0-0-0010654C00000-0-0-0010654C00000-0-0-00LC-MS 10654C00000-0-0-00peak location peak intensity ESES10654C00000-0-0-0010654C00000-0-0-00( NO3-) 10654C00000-0-0-00漿Agilent Technologies 5110ICP-O ES ( Si) ( Fe) pH10654C00000-0-0-005 漿10-25mL 60,000-65,000 rpm 1 使a . b .ICPc .HPLC d .LC-MS/MS 107 3 231070005012202 20 LC-MS ISO17025ISO17025peak location peak intensity 使LC-MS LC-MS 7 2 5 LC-MS 61.98651195.90480 241.89843 retention time ,R T 4.45-4.82 NO3-FeO NO3 2-FeNO3 3-LC-MS monoisotopoic mass241,898 241.899 31327 C5H7C15 C6N3S4CH4Cl2N2O4S2C2H5AgN3S2C4HC1NO5S2FeN3O9( Fe( NO3) 3)C4H7Cl4OP LC-MS LC-MS ISO17025 1 2.8 1 8 LC-MS 1 1211CMP 1 8 LC-MS 1 1619201 8 1 8 1 +2+3+2+3+2+31 LC-MS LC-MS TRC 1 1 131 13使0.005 0.201 280ppm Fe CMP 漿漿2 3000 ppm2ppm10ppm 10ppm 1 10ppm 使使ICP-OES 84ppm 0 100 150ppm6542171884ppm 60,000- 65,000( rpm) 1 7,887715調使調1 16EDTA使 2.10 1 108 8 8 LC-MS 1619201 10 3.11 1 11101010LC-MS 1 111 111 11 4.21 1 211 8 9 218 8 1 8 LC-MS 1 211210111 21211 215.22 1 2221211 21LC-MS 1 22221 22 6.24 1 241 8 9 248 8 0.001 2.0 1 248 10ppm 283 ppm 43.3ppm 0.00431 240.001 2.0 1 24 ICP-OES N03-LC-MS ICP-OES LC-MS IC 7.28 1 281 8 9 288 8 1 8 O SiO Siat% 69.24 30.76 65.73 34.27 68.40 31.60 2:1 EDS SiO21 281 1314171 281 28 8.29 1 29282828SiO21 291 1314171 291 29 9.30 1 3029291 3029SiO21 301 30 10.31 1 31282828SiO21 3131 11.34 1 3428285 / 430 / 1 28漿152.0 /gBET 1 345 / 430 / 1 34 12.35 1 35342830/ 170 / 1 3534漿152.0 /g1 3530/ 170 / 1 35 1 1 4 9 111521222428313435 1.1 1 1 -O-O- LC-MS 1 1 -O-O- MSDS105 11105 5 5 使-O-O- 1 10111 IV-O-O- 使使-O-O --O-O -102 5 241 1 -O-O- MSDS使-O-O- 使-O-O- 使使1 1 -O-O- 185 使使使1 1 -O-O- 1 1 2.4 1 4 1 1 1 1 1 4 1 1 4 3.9 1 9 -O-O- 1 9 LC-MS 1 9 -O-O- MSDS使-O-O- 1 10111 ( IV) -O-O- 使-O-O- -O-O- 102 5 24-O-O- 1 9 4.10111521222428313435 1 101115212224283134351 9 1 9 1 1 9 1 1011152122242835 2 1 6 111317242728303234713 1.2 1 2 1 2 6 1113172427283032341 2 11 2 21221 漿8 pyrazole漿14 pryidine漿302,5--1,3- 2,5-dimercapto-1 ,3-thiadizaole)2 1 2 112,5--1,3- 2 使 2.2,3,5-2- 2 1 CMP 漿CMP 漿2,3,5-2- 3 2 1 漿2 漿11漿242 1 漿8 漿142,5--1,3- 漿47漿2 漿11漿24漿8 漿 142,5--1 ,3-漿472,3,5- 2-漿8 漿142,5--1 ,3-漿47CMP 漿CMP 漿2 11 1 1 3.2 使2 1 6 111317242728303234713 1 1 4 8 9 10111521222428313435713 1 2 3 1 8 1011212224283134351 106 1125滿1 2 1 6 111317242728303234713 2 使DS W-2500 漿Chemical-Mechanical Planarization Slurry116769漿198297 1 78         107    6     13   20         107    6     13