ANNEX IVSupplementary provisions
ANNEX IV Annex IV to Regulation (EC) No 1272/2008 is amended as follows: (1) The first introductory paragraph of Annex IV is replaced by the following: ‘This Annex sets out a matrix listing the recommended precautionary statements for each hazard class and hazard category by type of precautionary statement. The matrix guides the selection of appropriate precautionary statements, and includes elements for all categories of precautionary action. All specific elements relating to particular hazard classes shall be used. In addition, general precautionary statements not linked to a certain hazard class or category shall also be used where relevant. To provide flexibility in the application of precautionary phrases, combinations or consolidations of precautionary statements are encouraged to save label space and improve readability. The matrix and the Tables in Part 1 of this Annex include a number of combined precautionary statements. However, these are only examples and suppliers may further combine and consolidate phrases where this contributes to clarity and comprehensibility of label information in accordance with Articles 22 and 28(3). Notwithstanding Article 22 the precautionary statements that appear on labels or in safety data sheets may incorporate minor textual variations from those set out in this Annex where these variations assist in communicating safety information and the safety advice is not diluted or compromised. These may include spelling variations, synonyms or other equivalent terms appropriate to the region where the product is supplied and used.’ (2) Table 6.1 is amended as follows: The entry concerning code P103 is replaced by the following: ‘P103 Read carefully and follow all instructions. as appropriate Consumer products – omit where P202 is used ’ (3) Table 6.2 is amended as follows: (a) The entries concerning codes P201 and P202 are replaced by the following: ‘P201 Obtain special instructions before use. Explosives (section 2.1) Unstable explosive Germ cell mutagenicity (section 3.5) 1A,1B, 2 Consumer products – omit where P202 is used ’ Carcinogenicity (section 3.6) 1A,1B, 2 Reproductive toxicity (section 3.7) 1A,1B, 2 Reproductive toxicity — effects on or via lactation (section 3.7) Additional category P202 Do not handle until all safety precautions have been read and understood. Flammable gases (section 2.2) A, B (chemically unstable gases) Germ cell mutagenicity (section 3.5) 1A,1B, 2 Carcinogenicity (section 3.6) 1A,1B, 2 Reproductive toxicity (section 3.7) 1A,1B, 2 Reproductive toxicity, effects on or via lactation (section 3.7) Additional category (b) The entry concerning code P210 is replaced by the following: ‘P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.4, 1.5 Flammable gases (section 2.2) 1A, 1B, 2 Aerosols (section 2.3) 1, 2, 3 Flammable liquids (section 2.6) 1, 2, 3 Flammable solids (section 2.7) 1, 2 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Oxidising liquids (section 2.13) 1, 2, 3 Oxidising solids (section 2.14) 1, 2, 3 Organic peroxides (section 2.15) Types A, B, C, D, E, F Desensitised explosives (section 2.17) 1, 2, 3, 4’ (c) The entry concerning code P212 is inserted: ‘P212 Avoid heating under confinement or reduction of the desensitising agent. Desensitised explosives (section 2.17) 1, 2, 3, 4’ (d) The entry concerning code P222 is replaced by the following: ‘P222 Do not allow contact with air. Flammable gases (section 2.2) Pyrophoric gas — if emphasis of the hazard statement is deemed necessary .’ Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 (e) The entry concerning code P230 is replaced by the following: ‘P230 Keep wetted with … Explosives (section 2.1) Divisions 1.1, 1.2, 1.3, 1.5 Manufacturer/supplier to specify appropriate material — for substances and mixtures which are wetted, diluted, dissolved or suspended with a phlegmatiser in order to suppress their explosive properties Desensitised explosives (section 2.17) 1, 2, 3, 4 Manufacturer/supplier to specify appropriate material’ (f) The entry concerning code P233 is replaced by the following: ‘P233 Keep container tightly closed. Flammable liquids (section 2.6) 1, 2, 3 — if the liquid is volatile and may generate an explosive atmosphere Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Desensitised explosives (section 2.17) 1, 2, 3, 4 Acute toxicity – inhalation (section 3.1) 1, 2, 3 — if the chemical is volatile and may generate a hazardous atmosphere’ Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity – single exposure; narcotic effects (section 3.8) 3 (g) The entry concerning code P280 is replaced by the following: ‘P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… Explosives (section 2.1) Unstable explosive and divisions 1.1, 1.2, 1.3, 1.4, 1.5 Manufacturer/supplier to specify the appropriate type of personal protective equipment. Flammable gases (section 2.2) Pyrophoric gas Flammable liquids (section 2.6) 1, 2, 3 Flammable solids (section 2.7) 1, 2 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Self-heating substances and mixtures (section 2.11) 1, 2 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 Oxidizing liquids (section 2.13) 1, 2, 3 Oxidizing solids (section 2.14) 1, 2, 3 Organic peroxides (section 2.15) Types A, B, C, D, E, F Desensitised explosives (section 2.17) 1, 2, 3, 4 Acute toxicity – dermal (section 3.1) 1, 2, 3, 4 — Specify protective gloves/clothing. Manufacturer/supplier may further specify type of equipment where appropriate. Skin corrosion (section 3.2) 1A, 1B, 1C — Specify protective gloves/clothing and eye/face protection. Manufacturer/supplier may further specify type of equipment where appropriate. Skin irritation (section 3.2) 2 — Specify protective gloves. Manufacturer/supplier may further specify type of equipment where appropriate. Skin sensitisation (section 3.4) 1, 1A, 1B Serious eye damage (section 3.3) 1 — Specify eye/face protection. Manufacturer/supplier may further specify type of equipment where appropriate. Eye irritation (section 3.3) 2 Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Manufacturer/supplier to specify the appropriate type of personal protective equipment.’ Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 (4) Table 6.3 is amended as follows: (a) The entries concerning codes P301 and P302 are replaced by the following: ‘P301 IF SWALLOWED: Acute toxicity – oral (section 3.1) 1, 2, 3, 4 Skin corrosion (section 3.2) 1, 1A, 1B, 1C Aspiration Hazard (section 3.10) 1 P302 IF ON SKIN: Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2 Acute toxicity – dermal (section 3.1) 1, 2, 3, 4 Skin irritation (section 3.2) 2 Skin sensitisation (section 3.4) 1, 1A, 1B’ (b) The entry concerning code P332 is replaced by the following: ‘P332 If skin irritation occurs: Skin irritation (section 3.2) 2 may be omitted if P333 is given on the label.’ (c) The entry concerning codes P370 and P371 are replaced by the following: ‘P370 In case of fire: Explosives (section 2.1) Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5 Oxidising gases (section 2.4) 1 Flammable liquids (section 2.6) 1, 2, 3 Flammable solids (section 2.7) 1, 2 Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Pyrophoric liquids (section 2.9) 1 Pyrophoric solids (section 2.10) 1 Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 Oxidising liquids (section 2.13) 1, 2, 3 Oxidising solids (section 2.14) 1, 2, 3 Organic Peroxides (section 2.15) Types A, B, C, D, E, F Desensitised explosives (section 2.17) 1, 2, 3 P371 In case of major fire and large quantities: Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 Desensitised explosives (section 2.17) 4’ (d) The entry concerning code P375 is replaced by the following: ‘P375 Fight fire remotely due to the risk of explosion. Explosives (section 2.1) Division 1.4 — for explosives of division 1.4 (compatibility group S) in transport packaging.’ Self-reactive substances and mixtures (section 2.8) Type B Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 Organic peroxides (section 2.15) Type B Desensitised explosives (section 2.17) 1, 2, 3, 4 (e) The entry concerning code P377 is replaced by the following: ‘P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Flammable gases (section 2.2) 1A, 1B, 2’ (f) The entry concerning code P380 is replaced by the following: ‘P380 Evacuate area. Explosives (section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 Self-reactive substances and mixtures (section 2.8) Types A, B Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 Organic peroxides (section 2.15) Types A, B Desensitised explosives (section 2.17) 1, 2, 3, 4’ (g) The entry concerning code P381 is replaced by the following: ‘P381 In case of leakage, eliminate all ignition sources Flammable gases (section 2.2) 1A, 1B, 2’ (h) The entry concerning code P301 + P312 is replaced by the following: ‘P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell Acute toxicity – oral (section 3.1) 4 … Manufacturer/supplier to specify the appropriate source of emergency medical advice’ (i) The entries concerning codes P370 + P380 + P375 and P371 + P380 + P375 are replaced by the following: ‘P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Explosives (section 2.1) Division 1.4 — for explosives of division 1.4 (compatibility group S) in transport packaging’ Desensitised explosives (section 2.17) 1, 2, 3 P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Oxidising liquids (section 2.13) 1 Oxidising solids (section 2.14) 1 Desensitised explosives (section 2.17) 4 (5) Table 6.4 is amended as follows: (a) The entry concerning code P401 is replaced by the following: ‘P401 Store in accordance with … Explosives (section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 … Manufacturer/supplier to specify local/regional/national/international regulations as applicable.’ Desensitised explosives (section 2.17) 1, 2, 3, 4 (b) The entry concerning code P403 is replaced by the following: ‘P403 Store in a well-ventilated place. Flammable gases (section 2.2) 1A, 1B, 2 Oxidising gases (section 2.4) 1 Gases under pressure (section 2.5) Compressed gas Liquefied gas Refrigerated liquefied gas Dissolved gas Flammable liquids (section 2.6) 1, 2, 3 — for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere. Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F — except for temperature controlled self-reactive substances and mixtures or organic peroxides because condensation and consequent freezing may take place. Organic peroxides (section 2.15) Acute toxicity – inhalation (section 3.1) 1, 2, 3 — if the substance or mixture is volatile and may generate a hazardous atmosphere.’ Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity – single exposure; narcotic effects (section 3.8) 3 (6) Table 6.5 is amended as follows: (a) The entry concerning code P501 is replaced by the following: ‘P501 Dispose of contents/container to … Flammable liquids (section 2.6) 1, 2, 3 … in accordance with local/regional/national/international regulation (to be specified). Manufacturer/supplier to specify whether disposal requirements apply to contents, container or both.’ Self-reactive substances and mixtures (section 2.8) Types A, B, C, D, E, F Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) 1, 2, 3 Oxidising liquids (section 2.13) 1, 2, 3 Oxidising solids (section 2.14) 1, 2, 3 Organic peroxides (section 2.15) Types A, B, C, D, E, F Desensitised explosives (section 2.17) 1, 2, 3, 4 Acute toxicity – oral (section 3.1) 1, 2, 3, 4 Acute toxicity – dermal (section 3.1) 1, 2, 3, 4 Acute toxicity – inhalation (section 3.1) 1, 2, 3 Skin corrosion (section 3.2) 1, 1A, 1B, 1C Respiratory sensitisation (section 3.4) 1, 1A, 1B Skin sensitisation (section 3.4) 1, 1A, 1B Germ cell mutagenicity (section 3.5) 1A, 1B, 2 Carcinogenicity (section 3.6) 1A, 1B, 2 Reproductive toxicity (section 3.7) 1A, 1B, 2 Specific target organ toxicity – single exposure (section 3.8) 1, 2 Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8) 3 Specific target organ toxicity – single exposure; narcotic effects (section 3.8) 3 Specific target organ toxicity – repeated exposure (section 3.9) 1, 2 Aspiration hazard (section 3.10) 1 Hazardous to the aquatic environment – acute aquatic hazard (section 4.1) 1 Hazardous to the aquatic environment – chronic aquatic hazard (section 4.1) 1, 2, 3, 4 (b) The following new entry is inserted after code P502: ‘P503 Refer to manufacturer/ supplier/… for information on disposal/recovery/ recycling Explosives (section 2.1) Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 … Manufacturer/supplier to specify appropriate source of information in accordance with local/regional/national/international regulations as applicable.’ (7) Table 1.2 is amended as follows: (a) The following new entry is inserted: ‘P212 Language BG Да се избягва нагряване в затворено пространство или понижаване на съдържанието на десенсибилизиращия агент. ES Evitar el calentamiento en condiciones de aislamiento o la reducción del agente insensibilizante. CS Zamezte zahřívání v uzavřeném obalu nebo snížení objemu znecitlivujícího prostředku. DA Undgå opvarmning under indeslutning eller reduktion af det desensibiliserende middel." DE Erhitzen unter Einschluss und Reduzierung des Desensibilisierungsmittels vermeiden. ET Vältida suletuna kuumutamist ja desensibilisaatori vähenemist. EL Να αποφεύγεται η θέρμανση σε περιορισμένο χώρο και η μείωση του παράγοντα απευαισθητοποίησης. EN Avoid heating under confinement or reduction of the desensitising agent. FR Éviter d'échauffer en milieu confiné ou en cas de diminution de la quantité d'agent désensibilisateur. GA Seachain an téamh i limistéar iata nó i gcás laghdú ar an dí-íogróir. HR Izbjegavati zagrijavanje u zatvorenom prostoru ili smanjenje udjela desenzitirajućeg agensa. IT Evitare di riscaldare sotto confinamento o di ridurre l'agente desensibilizzante. LV Nepieļaut karsēšanu slēgtā vidē vai desensibilizējošā aģenta daudzuma samazināšanos.” LT Vengti kaitimo uždaroje talpykloje arba desensibilizacijos veiksnio poveikio sumažėjimo. HU Kerülje a hevítést zárt térben vagy a deszenzibilizáló szer mennyiségének csökkenése esetén. MT Evita t-tisħin fil-magħluq jew it-tnaqqis tal-aġenti disensitizzanti. NL Vermijd verwarming onder opsluiting of vermindering van de ongevoeligheidsagens. PL Unikać ogrzewania pod zamknięciem lub w sytuacji zmniejszonej zawartości środka odczulającego.” PT Evitar o aquecimento em ambiente fechado ou a redução do agente dessensibilizado.» RO A se evita încălzirea în mediu confinat sau în caz de scădere a agentului de desensibilizare SK Zabráňte zahrievaniu v ohraničenom priestore alebo zníženiu obsahu desenzibilizačného činidla. SL Izogibati se segrevanju v zaprtem prostoru ali zmanjšanju vsebnosti desenzibilizatorja.“. FI Vältettävä kuumentamista suljetussa astiassa tai flegmatointiaineen vähentämistä. SV Undvik uppvärmning i sluten behållare eller reducering av det okänsliggörande ämnet.’