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Directive (EU) 2022/431 of the European Parliament and of the Council of 9 March 2022 amending Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens or mutagens at work ANNEX

ANNEX附則

ANNEX The Annexes to Directive 2004/37/EC are amended as follows: (1) in Annex III, point A is amended as follows: (a) the row related to benzene is replaced by the following: Name of agent EC No ( 1 ) CAS No ( 2 ) Limit values Notation Transitional measures 8 hours ( 3 ) Short-term ( 4 ) mg/m 3 ( 5 ) ppm ( 6 ) f/ml ( 7 ) mg/m 3 ppm f/ml ‘Benzene 200-753-7 71-43-2 0,66 0,2 – – – – Skin ( 8 ) Limit value 1 ppm (3,25 mg/m 3 ) until 5 April 2024. Limit value 0,5 ppm (1,65 mg/m 3 ) from 5 April 2024 until 5 April 2026.’ (b) the following rows are added: Name of agent EC No  ( 1 ) CAS No  ( 2 ) Limit values Notation Transitional measures 8 hours  ( 3 ) Short-term  ( 4 ) mg/m 3  ( 5 ) ppm  ( 6 ) f/ml  ( 7 ) mg/m 3 ppm f/ml ‘Acrylonitrile 203-466-5 107-13-1 1 0,45 – 4 1,8 – Skin  ( 8 ) Dermal sensitisation  ( 9 ) The limit values shall apply from 5 April 2026. Nickel compounds – – 0,01  ( 10 ) 0,05  ( 11 ) – – – – – Dermal and respiratory sensitisation  ( 12 ) The limit value  ( 10 ) shall apply from 18 January 2025 The limit value  ( 11 ) shall apply from 18 January 2025. Until then a limit value of 0,1 mg/m 3  ( 11 ) shall apply. Inorganic lead and its compounds     0,15               N,N-Dimethylacetamide 204-826-4 127-19-5 36 10   72 20   Skin  ( 8 )   Nitrobenzene 202-716-0 98-95-3 1 0,2         Skin  ( 8 )   N,N Dimethylformamide 200-679-5 68-12-2 15 5   30 10   Skin  ( 8 )   2-Methoxyethanol 203-713-7 109-86-4   1         Skin  ( 8 )   2-Methyoxyethyl acetate 203-772-9 110-49-6   1         Skin  ( 8 )   2-Ethoxy ethanol 203-804-1 110-80-5 8 2         Skin  ( 8 )   2-Ethoxyethyl acetate 203-839-2 111-15-9 11 2         Skin  ( 8 )   1-Methyl-2-pyrrolidone 212-828-1 872-50-4 40 10   80 20   Skin  ( 8 )   Mercury and divalent inorganic mercury compounds including mercuric oxide and mercuric chloride (measured as mercury)     0,02               Bisphenol A; 4,4′-Isopropylidenediphenol 201-245-8 80-05-7 2  ( 13 )               Carbon monoxide 211-128-3 630-08-0 23 20   117 100       (2) the following annex is inserted: ‘ANNEX IIIa BIOLOGICAL LIMIT VALUES AND HEALTH SURVEILLANCE MEASURES (Article 16(4)) 1. Lead and its ionic compounds 1.1. Biological monitoring must include measuring the blood-lead level (PbB) using absorption spectrometry or a method giving equivalent results. The binding biological limit value is: 70 μg Pb/100 ml blood 1.2. Medical surveillance is carried out if exposure to a concentration of lead in air is greater than 0,075 mg/m 3 , calculated as a time-weighted average over 40 hours per week, or a blood-lead level greater than 40 μg Pb/100 ml blood is measured in individual workers. ’. ( 1 )   EC No, i.e. Einecs, ELINCS or NLP, is the official number of the substance within the European Union, as defined in Section 1.1.1.2 in Annex VI, Part 1, to Regulation (EC) No 1272/2008. ( 2 )   CAS No: Chemical Abstract Service Registry Number. ( 3 )   Measured or calculated in relation to a reference period of eight hours time-weighted average (TWA). ( 4 )   Short-term exposure limit (STEL). A limit value above which exposure should not occur and which is related to a 15-minute period unless otherwise specified. ( 5 )   mg/m 3 = milligrams per cubic metre of air at 20 °C and 101,3 kPa (760 mm mercury pressure). ( 6 )   ppm = parts per million by volume in air (ml/m 3 ). ( 7 )   f/ml = fibres per millilitre. ( 8 )   Substantial contribution to the total body burden via dermal exposure possible. ( 9 )   The substance can cause sensitisation of the skin. ( 10 )   Respirable fraction, measured as nickel. ( 11 )   Inhalable fraction, measured as nickel. ( 12 )   The substance can cause sensitisation of the skin and of the respiratory tract. ( 13 )   Inhalable fraction.’;

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